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introduction of more reliable interferometers, the dispersive type was the most widely used FT spectrophotometers are preferred for many applications because of their speed, reliability, and convenience They have largely displaced other equipments in the analytical laboratories Source radiation is split into two beams whose path lengths can be varied periodically to produce interference patterns The reversed FT algorithm is then used for data recovery Early FT spectrometers required frequent adjustments of the optical parts, but their unique characteristics of speed, high resolution, sensitivity, and wavelength precision and accuracy made them indispensable Recent instrument design is much more reliable and easier to adjust Typically, FT spectrometers are based on the Michelson interferometer (Figure 14), although other types of optical systems are also encountered Laboratory FT spectrometers are usually proposed as single-beam instruments.

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For determining transmittance or absorbance spectra with this type of instrument a reference interferogram, air, for example, must rst be measured and stored The analyzed sample is then placed in the radiation path and the process repeated Transmittance at various frequencies is obtained by computing the ratio of the sample and reference spectra Over most of the MIR spectral range, FT instruments appear to have better signal-to-noise ratios than do good-quality dispersive instruments by more than one order of magnitude The enhanced signal-to-noise ratio can, of course, be traded for rapid scanning, producing spectra within a few seconds Interferometric instruments also feature high resolutions (less than 01 cm 1), high accuracy, and reproducible frequency determinations FT instruments provide a much larger energy throughput (one or two orders of magnitude) than do dispersive instruments, which are limited in throughput by the necessity of narrow slit widths.

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However, this advantage is partially offset by the lower sensitivity of fast-response detectors required for interferometry To perform chemical imaging of sample surfaces, FT spectrometers can be coupled with a microscope or macrochamber with an FPA detector CIS are available for Raman, NIR, and MIR spectroscopy Figure 15 illustrates an optical arrangement for chemical imaging Instrument design depends on how measurements are performed (Figure 10) The ideal instrument has both transmittance and re ectance capabilities For.

Figure 7-7: The result of Alt-clicking and clicking more than 40 times on the photo shown in Figure 7-6. I also cropped the image and added a border.

providing a platform for sharing best practices and knowledge. As organizations grow in complexity, additional management may be required to ensure that the elements of the QMS are integrated, functioning, and delivering the results expected.

Restrictions on lattice constants a a a a a a a a = b = c; = b = c; = b = c; = b = c; = b = c; = b = c; = b = c; = b = c; = = = = = = = = = = 90 ; = 90 = = 90 = = 90 = 90 ; < 120 = = 90 = 90 ; = 120 = = 90

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The sound and build quality of both manufacturers units are as good as you might expect, but for the price and, considering the restricted capabilities of these hi-fi computer wannabees, we would argue for buying or building and then deploying a multimedia PC Units like the Marantz and Yamaha do look nice and offer an easy way of getting hi-fi sound on your network, but they are really for people who have a high-end hi-fi system and want to have this component match the d cor of the other components in the rack Any personal computer with a decent audio card can serve as an audio server A variety of software can be used to serve up audio, including MusicMatch Jukebox, QuickTime, RealOne, WinAmp, Windows Media Player, iTunes, and others This category of software was last reviewed by PC Magazine in March 2003 and can be found online at www.

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Figure 5.38. Pulsed eld gel electrophoresis. DNA fragments are exposed to an electric eld which alternates in different directions as a result of electrical pulses. The DNA moves through the gel in response to this eld. Small molecules move more quickly than large ones due to their shorter visceoelastic relaxation times. For simplicity, an array of only four electrodes carrying equal charge is shown. In reality, the array may consist of many electrodes arranged in various geometries (Figure 5.40 5.43) and carrying different proportions of the current thus generating a complex electric eld. Separation is optimised by varying the pulse-time, homogeneity and geometry of the eld.

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